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Poly(methyl methacrylate)

Created by: Emily Nattrass & Natalie Tran
by

Iyma Lamarche

on 9 January 2013

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Transcript of Poly(methyl methacrylate)

Poly(methyl methacrylate) What is Poly(methyl methacrylate)?
(PMMA) A transparent thermoplastic
Lightweight and shatter-resistant
Acrylic glass under the brand names:
Plexiglas
Perspex
Lucite
Optix
Acrysteel
Altuglas (European)
Oroglas (European)
Synthetic polymer of methyl methacrylate
Alternative to glass and polycarbonate Production Obtain monomer substance: methyl methacrylate * * Methyl methacrylate Organic compound with formula
CH2=C(CH3)COOCH3
Formed from acrylic acid
Methyl ester of methacrylic acid (MMA)
A clear liquid substance
Other uses: methylmetacrylate-butadiene-styrene (MBS), polyvinyl chloride (PVC)
Hazardous History of Poly(methyl methacrylate) Different Uses Glass Alternative Medical Art/Aesthetic Works Cited Today 1843 1939 -1943 1933 1865 1877 Australian Government Department of Health and Ageing. NICNAS Existing Chemicals Information Sheet (2009, September). Methyl Methacrylate (MMA) in Cosmetic Nail Preparations. Retrieved January 8, 2012 from <http://www.nicnas.gov.au/publications/>

Gubera, J. (2012, January). Recycling Acrylic - Polymethyl Methacrylate (PMMA) Waste / Scrap in the USA. Plastic Recycling in the USA / China Markets. Retrieved January 7, 2012 from <http://dualloy.blogspot.ca/2010/0 1/recycling-acrylic-polymethyl.htm >

Library of Congress Prilinger Archive (Distributer). (2012). Youtube [Plexiglas: "Looking ahead through Plexiglas" 1947 Rohm & Haas poly(methyl methacrylate) PMMA]. Retrieved Jaunuary 8, 2012 from <http://www.youtube.com/watch?v=TqD281UFfdA>

The Universities of Southern Nipissing. (2005). Poly(methyl methacrylate). Retrieved January 7, 2012 from < http://pslc.ws/mactest/pmma.htm>.

Work Safe Alberta. (2009). Workplace Health and Safety Bulletin. Use of Methyl Methacrylate - Containing Products for Fingernail Sculpting. Retrieved January 7, 2012 from <humanservices.alberta.ca/documents/WHS-PUB_ch062.pdf>.

N.a. (N.d.). Acrylic plastic. How Products Are Made Volume 2. Retrieved January 8, 2012 from <http://www.madehow.com/Volume-2/Acrylic-Plastic.html>
Propylene Free Radical Polymerization:

Solution
Emulsion
Bulk Where From Synthesis [CH2C(CH3)(CO2CH3)]n The first acrylic acid was created CH2=CHCO2H Methacrylic acid is formulated Ferdinand Redtenbacher oxidized acrolein with aqueous silver oxide and isolated acrylic acid The reaction between methacrylic acid and methanol results in the ester, methyl methacrylate (MMA). German chemists Fittig and Paul discover the polymerization process that turns methyl methacrylate into polymethyl methacrylate German chemist Otto Rohm, of "Rohm & Haas", patented and registered the brand name Plexiglas. World War II Acrylic glass was used for
submarine periscopes
windshields, canopies, and gun turrets of airplanes Today PMMA is used in a wide variety of objects. It is easily made and affordable. Facts The monomer methyl methacrylate is considered toxic to human beings It is banned in Canada, 30 states in the US, New Zealand, and Australia Properties Lightweight
Transparency: 92%
Refractive Index: 1.49
Temperatures:
M.P. = 160°C
G.T.T. = 105°C
Ignite = 460°C
Hockey Rink Porthole Police Car Bank Teller Aquarium Dental Filling Injection Bone Cement Intraocular Lens Sunlight Redirection Plaque/Award Instrument Furniture Fashion Isopropyl benzene Petroleum Acetone Methyl methacrylate Recycling/Safety PMMA: Not hazardous MMA: Allergenic and toxic (fumes) Controlled Environment No Traces in
Biomedical Use Not biodegradable
Recyclable through heat or pyrolysis

However:
Cannot be used as clear acrylic glass
Full transcript