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Chemistry

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Tara Stolen

on 27 August 2015

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Transcript of Chemistry

Chemistry
Observations & Inferences
What is Chemistry?
Chemistry is a branch of science which describes matter & the changes in matter.
Measurement - Quantitative Observations
How do we solve problems?
Scientific method - organized step-by-step thought process used to solve a problem
Unit 1: Introduction to the Scientific Method & Measurement
A scientific
observation
may involve seeing, feeling, hearing, or using a measuring device. Scientists carefully record observations as part of the scientific process. Analysis of observations allows the scientist to infer conclusions.
An
inference
is a logical conclusion based on observation or deductive reasoning.
Inductive vs. Deductive Reasoning
Science is the study of the world around us. Science - searching for a cause & effect.

Pure Science: For discovery & explanation

Applied Science/Technology: put discoveries to use - to better mankind - leads to more technology
Pure Science
Organic Chemistry
Inorganic Chemistry
Biochemistry
Physical Chemistry
Thermochemistry
Electrochemistry
Nuclear Chemistry
Applied Science
Medications
Smartphones
Internet
Agricultural Research
"Technology"
Problem
Research
Hypothesis
Experiment
Results
Conclusion
Define the problem (after observing a situation)
Research the problem
Past Experiments
Past Hypotheses & Laws
Form a hypothesis - a proposed explanation based on observations & prior knowledge

If (I do this), then (this will happen)
Design & perform tests (experiment)
Collect Data
Qualitative Data: (without numbers) a description in words of what is seen, felt, touched, heard
Ex: Round, green, fuzzy, loud

Quantitative Data: (with numbers) measurements
Ex: 23.5 cm, 61.83 mL
Search for relationships

Make graphs, calculations
Interpretation of Relationships
Evaluate the hypothesis
Either reject the hypothesis or support the hypothesis
YOU CAN NEVER PROVE A HYPOTHESIS 100%
Perform additional tests
Theory
A scientific theory is an explanation that is strongly supported by scientific evidence. Scientific theories are usually validated by repeated observation and experimentation. In short, scientific theories describe why things happen.
A law of nature is a statement that describes a natural phenomenon that always happens the same way under the same set of circumstances. Laws are descriptive. They do not explain the science behind the phenomenon. For example, all gases can be measured to behave similarly at the same temperature and pressure. This is a statement of fact, and it is described by the ideal gas law. In this example, the ideal gas law does not describe why this phenomenon occurs. Instead, it only describes what occurs
Law
Precision
Accuracy
The measurement can be repeatable by others. (All close to the same value)
Reliable
Repeatable
Reproducible

Someone else could use the same equipment and get the same measurement
Bunsen Burner
Wire Gauze
Bowl
Crucible Tongs
Test Tube Holder
Volumetric Flask
Crucible
Watch Glass
Ring Stand
Erlenmeyer Flask
Clay Triangle
Beaker
Test Tubes
Close to the accepted value
Observation
Interpretation
Data collected via qualitative (descriptions) or quantitative (numbers) methods are FACTS only.

Observations are made using one or more of your five senses.
An interpretation attempts to explain an observation.

Example: the light bulb glowed BECAUSE electricity was going through the filament, making it hot.
Significant Figures
Not all numbers are significant!
1. All non-zeros ALWAYS count
2. Trapped zeros ALWAYS count
3. Trailing zeros ONLY IF a decimal is present or a line over it
4. Zeros before the first 1-9 number NEVER count
Calculating with Significant Digits
Add/Subtract
Answer should have the # of decimal places as the number with the least number of decimal places because you cannot be more precise than the least precise number.
Ex: 2.65435 + 1.1 = 3.7
4.795 - 2.3 = 2.4
Multiply/Divide
Answer should have no more sig figs than the factor with the least number of significant figures - you can only be as precise as the least precise number.
Ex: 1.15 x 2.3 = 2.6
Derived Units
A unit made through a calculation of measurements

Ex: Measure the mass and volume and you can calculate the density.
Metric/
SI (international) Units
Each unit of measurement has a base that can have a different prefix added.
Length = meter (m)
Mass = gram (g)
Volume = liter (L)
Temperature = Celsius (c)
or Kelvin (K)
Time = Second (s)
Commonly Used Prefixes
Nano
Micro
Milli
Centi
Deci
Kilo
0.000,000,001
0.000,001
0.001
0.01
0.1
1000
1 billionth
1 millionth
1 thousandth
1 hundredth
1 tenth
1000 x larger
Scientific Notation
Scientific notation is how scientists easily handle very large or very small numbers.
Density = mass/volume
Density describes how much matter is in a certain amount of space.
Dimensional Analysis
(also called Factor-Label Method or the Unit Factor Method) is a problem-solving method that uses the fact that any number or expression can be multiplied by one without changing its value. It is a useful technique.
When to use Dimensional Analysis
Use this method when you are trying to change the units for a measurement (ex: inches to centimeters)
EX: Mrs. Polson is 63 inches tall. How many meters is that?

Hint: You need to know how many centimeters is in an inch, and how many centimeters are in a meter.
Given
Want
Units Cancel
Measuring Rules
1. Record a number for every line on the instrument.
2. When you run out of lines estimate the last digit
3. If it is right on the line estimate a zero
4. More lines = more accurate
When you use a graduated cylinder, read from the BOTTOM of the meniscus (curve)
Percentage Error
Percent error describes how far away from the expected value your result is, or how much error you have in your experiment.
% error =
True Value - Observed Value
True Vale
x 100
Percentage Error vs.
Testing Percentage
Say you got 52/61 on a test.... how do you calculate your percent?
% = 52/61 = 85%
What if you had to calculate the percent you got wrong?
% wrong = (#wrong)/61 = (61-52)/61
That's the same as percent error!
Graduated Cylinder
Buret
Warm-Up
The balloons from yesterday's experiment were filled with hydrogen, carbon dioxide, oxygen, a mixture of hydrogen and oxygen, helium, and air. Use the facts below and your observations to determine which balloon is which.
Densities
Hydrogen (H2): D = .000089 g/mL,
Carbon Dioxide (CO2): .001977 g/mL
Oxygen (O2): D = .001331 g/mL
Helium (He): D = .00018 g/mL,
Air (Mixture, mostly N2): .00128 g/mL
Flammable:
Hydrogen: Very flammable
Carbon Dioxide: No
Oxygen: No, but provides fuel for fire
Helium: No
Nitrogen (N2): No

Warm-Up Questions
1. You are measuring length with a meter stick. However, you do not realize that the first 4.0 centimeters of the meter stick are missing. How will your measurements be with respect to precision and accuracy?

2. Write your own example of a scenario that would give you inaccurate but precise measurements.

3. Agree or disagree with the following statement and explain your choice: "We can never be 100% certain of any measurement because at some point we'll reach the limit of precision. After that, it is all just a guess."
Warm-Up
2. How many significant figures does each number have?
A: 1,009.0
B: 0.000560
C: 4,300
D: 600,001
E: 5,600,320
1. Evaluate the accuracy and precision of classmate A and classmate B. (wait for demo)
Warm-Up: Quiz Practice
Write the following numbers using scientific notation.
1) 0.00000342
2) 19,800,000
3) 879,300,000
4) 0.000783

Write out the following number in full:
5) 2.14 x 10^-5
Answer the following problems (watch your SIG FIGS)
6. 1.12 mL + 0.465 mL =
7. 1.111111 g x 2 g =
8. 100.0 cm - 70.05 cm =
1) 0.00000342 => 3.42 x 10^-6
2) 1,9800,000 => 1.98 x 10^7
3) 879,300,000 => 8.793 x 10^8
4) 0.000783 => 7.83 x 10^-4
5) 2.14 x 10^-5 => .0000214
6) 1.12 mL + 0.465 mL
= 1.585 mL => 1.59 mL
7) 1.111111 g x 2 g
= 2.2222222 g => 2 g
8) 100.0 cm - 70.05 cm =
= 29.95 => 30.0 cm
Density Lab
Many years ago in a land far, far away a King was given a crown that he doubted the authenticity of. The King asked a man by the name of Archimedes to help him determine whether the crown was truly made of gold. Archimedes knew that the ratio between mass and volume remained constant for a pure substance.
Welcome to Saguaro Chemistry!
Mrs. Polson
(Stolen)
The Class
Science/Measurement
Classification of Matter
Atomic Structure
Periodic Table
Chemical Formulas & Equations
Solutions
Chemical Bonding & Kinetics
Thermodynamics
Acids, Bases, Salts & Titrations
Gas Laws
Oxidation-Reduction Reactions
Electrochemistry
SI UNITS
Mass = kilogram
Volume = cubic meter
Length = meter
Time = second
Electrical current = ampere
Temperature = Kelvin
Amount of substance = mole
Luminous intensity = candela
Density = kg/m^3
Kilo Hecto Deca (UNIT) Deci Centi Milli
1000000
.000001
Metric Units
Full transcript