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vulcanization
combine natural rubber with sulfur and heat to 132 degrees Celsius
Charles Goodyear discovers vulcanization. Vulcanized rubber is much more durable than its natural counterpart and so is commonly used in making tires.
Some polymers (e.g. tar and shellac) occur naturally and have then been processed by heat and pressure into useful things like hair and amber.
The first recorded synthetic plastic bakelite is formed serendipitously by Leo Bakeland.
British explorers discovered an ancient Mayan civilization who found one of the first application of polymers. They made balls for the children to play with using local rubber trees.
Bakelite
Bakelite has a high resistance to heat and is very hard, making it a useful electrical insulator
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