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HACETTEPE UNIVERSITY

CHEMICAL ENGINEERING DEPARTMENT

ETHYLENE GLYCOL DESIGN

AYLİN KANGALLI

AYŞE DİLARA AYDIN

SEHER BALKANLI

TUĞBA TUNÇEL

Ethylene glycol was first prepared in 1859 by the French chemist Charles-Adolphe Wurtz. It was produced on a small scale during World War I, for use as a coolant and as an ingredient in explosives.

ETHYLENE GLYCOL PROCESSES

APPLICATIONS OF ETHYLENE GLYCOL

Capacity : 89.000 Ton/Year MEG

Production Tecnology : In the Aliağa Complex entegrated

Ethylene Oxide / Ethylene Glycol Plant is "SHELL’s direct oxidation " process.

Products : Mono-ethylene Glycol (MEG) Di ethylene Glycol (DEG)

End Uses : Antifreeze, Polyester fiber, PET bottles, Textile Products and Explosive materials.

Price of EG : 1000-1200 $/t

Halcon Acetoxylatin Process

Alternative from Syn-Gas

Ethylene Glycol from Ethylene Chlorohydrins

Hydrolysis of Ethylene Carbonate (Shell OMEGA)

Hydrolysis of Ethylene Oxide

Polyester fibers & Fabric Industry

PET resins used in bottling

Antifreeze & Coolant

CAPACITY SELECTION

Hydrolysis of Ethylene Carbonate

(Shell OMEGA)

Alternative from Syn-Gas

Halcon Acetoxylatin Process

Ethylene Glycol from Ethylene Chlorohydrins

Hydrolysis of Ethylene Oxide

EQUIPMENT DESIGN

CAPACITY: 270000ton/year

REACTIONS

T-501 DISTILATTION COLUMN

2 C2H 4O + H2O CH 2OH - CH 2 OH + 22 kg.cal /gr. mol

Monoethyleneglycol ( MEG )

 

 

C2H 4O +MEG HOCH2–CH2-O-CH2–CH2OH +25 kg-cal/gr.mol

Diethyleneglycol ( DEG)

 

 

C2H 4O +DEG HOCH2-CH2-O-CH2-CH2-O-CH2-CH2OH +24 kg- cal/g.mol

Triethyleneglycol ( TEG)

First reaction:

CH 2 = CH 2 + 1/2 O 2 C2H4O

- Reaction caries out at 17,4 kg/cm 2 and 230 °C in fixed bed that has silver catalyst.

- Exothermic reaction.  

- Product are taken from the bottom of the

reactor at 240 0 C – 260 0 C

- Conversion is %2,5

ADVANTAGES OF MERSIN

DESIGN OF E-201 : EO ABSORBER

Devoloped harbor

Due to wind, more safety area

Suitable for sea transport of raw materials

Close to Polyester Fiber Industry

Large excess water

DESIGN OF R-401: GLYCOL REACTOR

Transportation of Raw Material

DESIGN OF R-301 : CO2 ABSORBER

LAY OUT

EQUIPMENT SUMMARY TABLE

P&ID INSTRUMENTATION

FRICTION LOSS OF PIPES

FLOW SUMMARY TABLE

ETHYLENE GLYCOL PLANT DESIGN

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