The Sulfur Cycle
Human Impact
- Burning of oil and coal to produce electrical power
- The process of smelting to convert sulfur compounds into metals such as Copper, Lead, and Zinc
- Refining petroleum, containing sulfur, in order to heating oil, gas, etc.
- Sulfur released into the atmosphere results in acid rain
Pathway Continued
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- Some of this sulfur is cycled back into the atmosphere through sea-spray
- The sulfur that remains in the ocean and is lost in the sea depths
Pathway of movement
- Cycle begins with the weathering of rocks that release sulfur
- When the sulfur comes in contact with the air it becomes sulfate
- Then the sulfate is transferred to plants and organisms and is converted to an organic form
- Animals then move the sulfate through the food chain by eating these organic materials
- When these organisms dies, they decompose and release sulfur into the atmosphere as sulfate
- Some sulfur enters the tissue of microorganisms
- Volcanoes, organic swamps, and evaporation of water release sulfur into the atmosphere
- The sulfur then settles back to the surface
- Runoff from lakes and streams then transfers sulfur into oceans where it is cycled by marine organisms
Inorganic and organic reservoirs for Sulfur
Organic
- Tissues of microorganisms
- Emitted by decomposition of organic matter
Inorganic:
- Soil
- Water
- Air
- Rocks and Minerals
- Vitamins
- Seawater
Chemical Reactions Involved
- Oxidation of sulfide and elemental sulfur (S) and related compounds to sulfate, SO42–.
- Reduction of sulfate to sulfide
- Mineralization of organic sulfur to the inorganic form, hydrogen sulfide, H2S.
- Sulfur is released into the atmosphere through natural processes such as volcanic eruptions, as a by-product of metabolism from bacteria, and from ocean sea-spray