Solutions
Works with
Pricing
Log in
Teams
Get started
Log in
Get started
Palmer.CHEM520.BenchmarkFinal
KP
by
Kaitlin Palmer
·
4 views
·
Updated Jul 2, 2020
Share
Embed
Create your own
Audio Transcript
Auto-generated
00:02 - 00:04
Hello and welcome to my lecture on barium sulfate.
00:05 - 00:06
Many Miss Kalen Bomber.
00:07 - 00:09
And I'm doing this for my camp by 20 course
00:10 - 00:13
gone Subs of analytical chemistry I hope this actually records
00:14 - 00:16
this time Let's go.
00:18 - 00:20
In this lecture, we will delve into the compound of
00:20 - 00:21
the wheat berry.
00:21 - 00:24
Um, something in two different applications for the compound will
00:24 - 00:28
be discussed as an overview will first discuss the physical
00:29 - 00:30
and chemical properties of barium selfie.
00:31 - 00:34
Then move on to the toxicological and safety information for
00:34 - 00:39
the compound, followed by the primary use of barium sulfate
00:40 - 00:43
and then the secondary application that I included in this
00:43 - 00:45
lecture. And we'll conclude with the list of my references.
00:51 - 00:53
I wanted to begin rec showing the physical structure of
00:53 - 00:54
barium sulfate.
00:54 - 00:57
It is a pretty simple compound, but I still wanted
00:57 - 00:58
to show this very himself.
00:59 - 01:01
It is just composed of the singular barium two plus
01:02 - 01:05
cat ion and the still fate to minus as a
01:05 - 01:07
four to minus Polly Atomic.
01:08 - 01:11
And I own I got this image from the pup
01:11 - 01:16
come website that I links below bury himself.
01:16 - 01:21
It appears the white or yellowish powder or crystals, and
01:21 - 01:24
that's why I included this image here, the barium sulphate.
01:25 - 01:29
The name itself has Ah, this anonymous with bear right,
01:29 - 01:33
which is the middle or version that Barrett, the very,
01:33 - 01:38
um solid that barium sulfate is found in nature that
01:38 - 01:39
included the molar mass.
01:39 - 01:43
Here it is a rather heavy element because rather heavy
01:43 - 01:47
compound due to barium being a rather heavy element, barium
01:48 - 01:52
got its name derived from the Greek embarrass for heavy
01:53 - 01:53
Harry himself.
01:54 - 01:58
It is the only insoluble version of barium, which is
01:58 - 02:02
significant for its health and talked toxicological information.
02:04 - 02:06
I included the melting point of very himself.
02:06 - 02:06
Eight here.
02:07 - 02:08
At this point, it does begin to decompose.
02:09 - 02:14
And then I also included the density moving on to
02:14 - 02:16
the chemical properties very himself.
02:17 - 02:23
Feet is the only insoluble form of their of barium,
02:24 - 02:27
and all other forms of barium are soluble in other
02:27 - 02:30
forms of barium is toxic to humans, but the variant
02:31 - 02:33
self, it is allowed to be safely ingested because of
02:33 - 02:35
its insoluble ity.
02:36 - 02:39
The primary use of barium sulfate is used in oil
02:40 - 02:40
well drilling fluid.
02:41 - 02:44
This is our primary application are secondary application I included
02:45 - 02:48
is medicinally barium sulphate is used in solution as a
02:48 - 02:50
radio opaque contrast agent.
02:51 - 02:57
Besides this Barry himself, it is also utilized in the
02:57 - 03:02
manufacturing of photographic papers, artificial ivory and cellophane as a
03:02 - 03:05
filler for rubber linoleum, oilcloth, poly meric fibers and resins,
03:06 - 03:09
paper and lithographic inks, as well as a water color
03:10 - 03:13
pigment for colored paper in wallpaper and as a pigment
03:14 - 03:17
in white paint, as well as as a hardening agent
03:17 - 03:17
in cement.
03:21 - 03:22
Moving on.
03:26 - 03:28
There is a great potential for toxicity to the human
03:28 - 03:32
body with barium sulphate, which I will discuss and then
03:33 - 03:33
barium sulfate.
03:34 - 03:37
Being the only in soluble form of barium does tend
03:38 - 03:40
to accumulate and remain in the soil and water.
03:49 - 03:53
Barium as a free ion, is readily absorbed by the
03:53 - 03:57
lung and or gastrointestinal tract and will accumulate in the
03:57 - 04:01
skeleton. Acute or chronic exposure to bury themselves can result
04:01 - 04:05
in a number of disorders, ranging from renal intoxication to
04:05 - 04:09
hypertension, cardiac malfunction and as well as hearing loss.
04:09 - 04:12
The kidneys are the most sensitive organ to barium, which
04:13 - 04:13
is wise specified.
04:14 - 04:21
The renal partney, sensitivity soluble and barium as an ion
04:21 - 04:24
is a muscle poison because barium is a physiological antagonised
04:25 - 04:29
of potassium, and we'll actually compete with and block the
04:29 - 04:32
potassium ion channels in the sodium, potassium pump and cell
04:33 - 04:37
membranes. Barium sulphate is also considered an irritant of the
04:37 - 04:41
eyes, nose and upper respiratory system, but it is non
04:41 - 04:43
combustible and poses no fire potential.
04:44 - 04:48
The Onley example of fire potential is thought is that
04:48 - 04:51
it's thought that heating it with aluminum can produce an
04:51 - 05:04
explosion moving on to the fate of barium sulfate in
05:04 - 05:05
the ecosystem and the in their environment.
05:07 - 05:10
In the water, barium sulfate is insoluble, so it will
05:10 - 05:14
remain. However, if barium is allowed to separate from from
05:15 - 05:18
the sulfate and I am and in bond to either
05:19 - 05:23
a nitrate chloride, carbonate or other soluble and ions, then
05:23 - 05:26
it will be able to leave the water easily, however,
05:27 - 05:27
otherwise bury himself.
05:28 - 05:33
Eight. It will just remain in the soil.
05:34 - 05:38
Under typical environmental conditions, barium will displace other ads.
05:39 - 05:43
Orb alkaline earth metals such as manganese, four oxide silicon
05:43 - 05:44
for oxide and titanium.
05:45 - 05:45
For oxide.
05:46 - 05:51
However, barium gets displaced from aluminum oxide by other alkaline
05:51 - 05:52
earth metals.
05:55 - 06:02
Moving on the primary application of himself is in Boy
06:02 - 06:04
isn't as is used as an additive to oil well
06:04 - 06:05
drilling fluids.
06:05 - 06:11
Almost 98% of Barry is used in this manner, and
06:11 - 06:15
it's done to make the oil well drilling fluid denser
06:16 - 06:18
and seal the space around the drill bent.
06:21 - 06:26
This creates a resultant mud, which is has a water
06:27 - 06:30
as a continuous phase, and water may contain several dissolve
06:30 - 06:35
substances, including alkali salts and surfactants, organic polymers, droplets of
06:35 - 06:39
the most wide oil and various insoluble substance to such
06:39 - 06:41
as bear right clearing cuttings in suspension.
06:43 - 06:46
Various thickening and suspending agents are added as well as
06:46 - 06:52
bear, right and um, this result into mud flushes.
06:52 - 06:56
Chip ings out and simultaneously cools and lubricates the drill
06:57 - 07:01
bit. However, with the addition of barium sulphate in the
07:01 - 07:04
oil well drilling, a scale will build up of the
07:04 - 07:08
compound in the oil and gas production systems and do
07:09 - 07:12
the barium sulfate, innate physical hardness and chemical and thermal
07:12 - 07:14
stability. It is one of the most difficult types of
07:14 - 07:15
scale to inhibit.
07:17 - 07:20
I'm very despite all this has been used, is awaiting
07:20 - 07:24
agent in drilling fluids since the 19 twenties and its
07:24 - 07:27
preferred over other materials because of its high density low
07:27 - 07:30
production costs, low abrasiveness and ease of handling.
07:31 - 07:33
Other waiting materials have been tried have been used, but
07:33 - 07:35
they are end up being problematic or costly.
07:37 - 07:42
So despite the consequence of the scale building up, Barrett
07:42 - 07:44
is still used in oil well drilling fluids.
07:46 - 07:49
I have included in ah, link to a YouTube video
07:50 - 07:57
which discusses this, um, waiting agent this this use of
07:57 - 07:59
Barry himself it as a waiting agent in the muds,
08:04 - 08:08
moving on to our second application of barium sulphate.
08:09 - 08:10
Barium self.
08:10 - 08:13
It is used as a contrast agent in radiography of
08:13 - 08:17
the G I tract, as I've already discussed, and I
08:17 - 08:23
will discuss the three examinations conducted and then we will
08:23 - 08:26
review one more time the consequence of soluble barium accumulation
08:27 - 08:28
in the human body.
08:31 - 08:37
Barium sulfate when drink and solution will coat the lining
08:37 - 08:41
of the gastrointestinal system, and it depends on what is
08:41 - 08:43
being examined for what is going to be coded.
08:44 - 08:45
There are three tests.
08:46 - 08:47
The barium swallow test or upper G I.
08:48 - 08:51
Siri's, the lower G I Siri's or the barium enema
08:51 - 08:53
and the small bowel followed through.
08:54 - 08:55
Each will diagnose different.
08:58 - 09:00
Each will diagnose different abnormalities.
09:01 - 09:05
Tumors, polyps, et cetera of the G I tract, the
09:05 - 09:07
barium swallow test, or upper G.
09:07 - 09:10
I will coat the esophagus and the stomach and diagnose
09:10 - 09:12
any abnormalities or anything there.
09:13 - 09:17
The lower G I series will coat the intestine and
09:17 - 09:18
will either be done.
09:18 - 09:20
It's a single contrast or a double contrast.
09:21 - 09:25
The single contrast image will diagnose any larger prominent abnormalities
09:26 - 09:29
in the large intestine, while the double contrast will bring
09:29 - 09:31
the light any of this smaller abnormalities in the large
09:31 - 09:35
intestine. The final barium eggs X ray is the small
09:35 - 09:41
bowel followed through, which illuminates the small intestine and for
09:42 - 09:43
any abnormalities.
09:43 - 09:46
Tallet tumors, polyps, et cetera.
09:51 - 09:53
I wanted to include an image of the study in
09:53 - 09:55
potassium pump in cellular membranes.
09:56 - 10:01
Here, uh, to further illustrate the effect of barium sulfate
10:03 - 10:07
inhibiting this active transportation across the cell membrane.
10:15 - 10:17
Finally, I wanted to include my references.
10:18 - 10:19
This video is shorter.
10:20 - 10:22
However, when I completed it the first time it got
10:23 - 10:23
to you
See full transcript