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Synthesis of Copolymers Contanining Mesitylborane for Organic Solar Cells

Bachelor project Aalborg university, section of chemistry
by

Rune Pedersen

on 21 June 2013

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Transcript of Synthesis of Copolymers Contanining Mesitylborane for Organic Solar Cells

Adamantane Benzophenone
Hydrofob gruppe
Microfiltration of Bovine Milk and Colostrum
by Sol-gel Modified Ceramic Membranes
by
Klaus Vedel Bjerrehus, Kaspar Kinnberg Christensen, Rebekka Bartholdy Neergaard, Rune Hansen Pedersen, Anders Ørts Tjell

Supervisor
Vittorio Boffa
Immune system
Immune system
Contamination
Cleaning
Controlling
Temperature
Flow
Time instead of volume
Poresize
Figure 1.1
Motivation
Synthesis of Copolymers Contanining Mesitylborane for Organic Solar Cells
A202
Spring 2013
Aalborg University
Synthesis
Mesitylboronic Acid
2,7-Bis(trimethylsilylethynyl)-9,9-dioctylfluorene

2,5-Diethynyl-3-octylthiophene
2,5-Diethynyl-3-octoxythiophene
Organic Solar Cells
Polymerization by Hydroboration
Borane
Stability
Tricoordinated
Mesitylborane
Reaction
Results
Yield
Figure 3.3
Figure 3.2
Figure 2.1
Figure 2.2
Table 3.1
Thesis
Figure 2.3
Figure 3.6
Figure 3.5
Figure 1.9
Figure 1.10
Figure 1.4
Figure 1.8
Figure 2.5
Figure 2.6
Figure 2.7
Figure 3.9
Reaction
Results
Figure 3.11
Figure 3.12
Figure 2.4
Figure 3.7
Figure 2.8
Figure 2.9
Figure 2.10
Reactions
Figure 1.1
Figure 1.2
Figure 1.3
2,5-diethynyl-3-octylthiophene
2,7-diethynyl-9,9-dioctylfluorene
2,5-diethynyl-3-octoxylthiophene
Mesitylborane
Buchwald-Hartwig Cross-coupling
Williamson Synthesis of Aryl Ethers
Stategic Applications of Named Reactions in Organic Synthesis by L. Kürti and B. Czakó p. 484
Stategic Applications of Named Reactions in Organic Synthesis by L. Kürti and B. Czakó p. 70
Other Methods
Thank you for your
attention!

Summary
Mesitylborane
2,7-Bis(trimethylsilylethynyl)-9,9-dioctylfluorene
2,5-Bis(trimethylsilylethynyl)-3-octylthiophene
2,5-Bis(trimethylsilylethynyl)-3-octyloxythiophene
Introduction
Picture from: http://free.clipartof.com/5-Free-Summer-Clipart-Illustration-Of-A-Happy-Smiling-Sun.jpg
Important properties
Smith et al.
2.TMS
1.
Figure C.2
Full transcript