Send the link below via email or IMCopy
Present to your audienceStart remote presentation
- Invited audience members will follow you as you navigate and present
- People invited to a presentation do not need a Prezi account
- This link expires 10 minutes after you close the presentation
- A maximum of 30 users can follow your presentation
- Learn more about this feature in our knowledge base article
Do you really want to delete this prezi?
Neither you, nor the coeditors you shared it with will be able to recover it again.
Make your likes visible on Facebook?
Connect your Facebook account to Prezi and let your likes appear on your timeline.
You can change this under Settings & Account at any time.
Molecular Structure & Chemical Reactivity
Transcript of Molecular Structure & Chemical Reactivity
http://aceorganic.pearsoncmg.com/epoch-plugin/public/mechmarvin.jsp The Rules of Resonance Resonance Practical Guidelines for Generating Resonance Contributors Common Mistakes Made in Drawing Resonance Contributors The Significance of Resonance Contributors The Molecular Orbital Model Shortcomings of the Lewis Model Electrostatics, Electron Density Distributions & Chemical Bonding Orbitals Are Represented as Isosurfaces The Orbitron Web Site
http://winter.group.shef.ac.uk/orbitron/ Wavefunctions Are Additive A Representation of LCAO Linear Combination of Atomic Orbitals The Orbitron Web Site
http://winter.group.shef.ac.uk/orbitron/ LCAO in Practice Sigma MOs http://butane.chem.illinois.edu/jsmoore/Jmol/SHEET1.html Disallowed Combinations http://butane.chem.illinois.edu/jsmoore/Jmol/SHEET1.html Pi MOs 10 Unique AO Combinations Trends in Orbital Energies MO Diagrams, Energy & Orbital Interactions MO Diagram of Fluorine MO Diagram of Carbon Monoxide Beyond Pairwise Combinations Interpreting the CO MO Diagram Nucleophiles, Electrophiles & the CO MO Diagram The Molecular Orbital Diagram of Carbon Monoxide http://www.stolaf.edu/people/hansonr/jmol/mo/ Hybrid Atomic Orbitals Hybridization MOs from Hybrid AOs Frontier Orbitals Filled Empty Orbital Interactions Curved Arrows & Frontier Orbitals Generalized Sigma & Pi Interactions Frontier Orbitals & Resonance Atoms in Molecules
are in Motion 3D Views to Represent
Conformation Molecular Structure,
Energy & Reactivity Anti & Gauche Conformational States Stereoisomers and the Time Scale of Interconversion Conformation http://www.chemaxon.com/marvin/sketch/index.php http://www.chem.fsu.edu/schwartz/CybermodelsJmol/jmolPages/JmolViewer2.html https://netfiles.uiuc.edu/jsmoore/www/Jmolpages/conformation/ConfViews.html http://www.chem.fsu.edu/schwartz/CybermodelsJmol/jmolPages/JmolViewer2.html http://www.chemaxon.com/marvin/sketch/index.php Cycloalkanes The Conformations
of Cycloalkanes Exploring the Conformations of Some Cycloalkanes The Conformations
of Cyclohexane The Cyclohexane Ring-Flip
A Minimum Energy Pathway Mono and Disubstituted
Cyclohexanes Reference: "Estimation of heats of formation of organic compounds by additivity methods," Chem. Rev. (1993) 93, 2419-2438. http://www.chemaxon.com/marvin/sketch/index.php http://www.chemaxon.com/marvin/sketch/index.php http://www.chem.ucalgary.ca/courses/351/Carey5th/Ch03/ch3-06.html http://www.chem.ucalgary.ca/courses/351/Carey5th/Ch03/ch3-06.html http://wetche.cmbi.ru.nl/organic/cyclohexane/jm/mecyc.html http://www.chemaxon.com/marvin/sketch/index.php The Proton Transfer [pt] Step and General Principles of Reactivity Nucleophiles & Electrophiles The Proton Transfer [pt] Step The Reaction Coordinate Diagram Transition State Structures The Proton Transfer Step on a Reaction Coordinate Diagram https://netfiles.uiuc.edu/jsmoore/www/09fa/notes/chem232fa09_packet.pdf Get the Notes! this is a 60 Mb pdf file Reactivity Concepts Structure-Reactivity Relationships Bond Energy Changes Nucleophiles & Reactivity Electrophiles & Reactivity Recognizing Acids & Bases Tools for Estimating pKa Acid-Base Equilibria The Mechanism Calculator Acidic & Basic Reagents Conventions Used in Writing Organic Reactions Acids & Bases in Organic Chemistry Substitution at sp3 Carbon Classes of Reactions Examples of Substitution Reactions [SN2] [AN] [DN] & Substitution Mechanisms [SN1] vs. [SN2] Substitution and the Electrophile Substitution and the Nucleophile Elimination at sp3 Alkene Stability Trends [E2], [DE] & [Ebeta] Steps The [E2] Mechanism The [E1] Mechanism Exceptions to Elimination Regiochemistry